Pardon me for being stupid but I don't quite understand the diagram. What is pin 40 and what does it do? Which pins on the resistor get wired up and where to? Also, what is the part marked with a 100 coming off of the transistor?
Pin 40 is luma (brightness) on the HuC6260 chip. On the transistor (not a resistor), assuming it's a standard 2N3904, you wire up the middle pin (base) to pin 40 on the HuC6260, the left pin (emitter) goes to a 100 ohm resistor and then to the luma pin on your S-video jack, and the right pin (collector) goes to 5V, which can be found on the HuCard slot or various other places on the board.
For chroma (color), take the composite video signal, wire it up to a 0.001 uF ceramic cap, and the other end goes to the chroma pin on the S-video jack.