Ok, so I was messing around again today with this.
I modded my Super CD-Rom 2 system for RGB output. Instead of pulling Composite Sync from pin one on the Din socket I cut off the leg so it wouldn't go through the PCB mounting hole.
I then ran a wire from the remaining Din socket leg to pin 22 on the expansion bus.
Now, in hindsight, I have no idea if pin 22 is Composite Sync or C-Sync. If pin 22 on the expansion bus is composite sync is it possible to get pure sync from someplace on the expansion bus port?
I was using this diagram of the expansion bus.
http://www.gamesx.com/misctec/pcebp.phpEdit:After some more poking around I decided to continuity test from pin 44 on the 6280A on my SuperGrafx to the same pin on the expansion port and I had sound. So it is CSync (pure sync) on pin 22-C and not composite sync. It seems to work just fine where it wouldn't on my TurboDuo.
I plan on getting some SS's of this system with CSync to compare it to one with composite sync. I also have a Component mod chip here from Turbokon and if I get some free time I will slap that into a system so I can get a 3way compare on my framemeister.