http://gamesx.com/wiki/doku.php?id=hu6260_netlistOK, going by that, pin 39 is GND (next to pin 40/Luma), pin 48 is GND (in between Red and Green), etc. There are several.
Use a DMM and do a continuity test to make sure with a known ground point and I guess I would solder directly on one of those pins.
The video socket's 5V is pretty close to the regulator so I think its OK, unless steve suggests otherwise.
Well, that's where a +5V source is normally taken on the top of the PCB and you've had reports of the problems with this region mod/flashcart issue which are solved by tapping the output pin of one of the regulators, etc. But yeah, I guess it's a matter of "juice" and this is a little amplifier, so probably not necessary to go that far.
EDIT: OK, here's some context,
a thread about the +5V regulator/switchless region mod issue. Just so you know what I was referring to. People report they fixed some crashes/issues with flashcarts and that region mod or whatever. Drakon says he always taps +5V from the regulator, etc. Your voltage will likely read higher, ~5.32 V or so whereas the at the AV out, I was getting like 5.02 V, etc.